王文忠, 孔 建, 曾鑫年, 李谱超. 松脂基植物油的农用溶剂性能研究[J]. 华南农业大学学报, 2013, 34(1): 32-36. DOI: 10.7671/j.issn.1001-411X.2013.01.007
    引用本文: 王文忠, 孔 建, 曾鑫年, 李谱超. 松脂基植物油的农用溶剂性能研究[J]. 华南农业大学学报, 2013, 34(1): 32-36. DOI: 10.7671/j.issn.1001-411X.2013.01.007
    WANG Wenzhong, KONG Jian, ZENG Xinnian, LI Puchao. Characters of Pine Oleoresin-Based Plant Oils as Solvents for Pesticide Formulation[J]. Journal of South China Agricultural University, 2013, 34(1): 32-36. DOI: 10.7671/j.issn.1001-411X.2013.01.007
    Citation: WANG Wenzhong, KONG Jian, ZENG Xinnian, LI Puchao. Characters of Pine Oleoresin-Based Plant Oils as Solvents for Pesticide Formulation[J]. Journal of South China Agricultural University, 2013, 34(1): 32-36. DOI: 10.7671/j.issn.1001-411X.2013.01.007

    松脂基植物油的农用溶剂性能研究

    Characters of Pine Oleoresin-Based Plant Oils as Solvents for Pesticide Formulation

    • 摘要: 分析测定了松脂基植物油的闪点、挥发性、农药溶解性及对农药稳定性的影响等主要农用溶剂性能指标,为松脂基植物油替代轻芳烃类溶剂用于农药制剂生产提供科学依据.研究结果表明,供试的4种松脂基植物油的闪点均大于35 ℃,明显高于对照溶剂二甲苯的25 ℃;在25 ℃下,供试的4种松脂基植物油8 h后的挥发率小于45.9%,其中ND-100的挥发率最低,为2.1%,而对照溶剂二甲苯的挥发率达100%.松脂基植物油ND-60对甲氨基阿维菌素苯甲酸盐、苯丁锡、氟硅唑、戊唑醇、高效氯氟氰菊酯和三唑锡6种农药原药的溶解性优于对照溶剂二甲苯,占供试农药的12.8%,而对多杀菌素和杀扑磷等15种农药原药的溶解性明显不及二甲苯,占供试农药的31.9%.松脂基植物油ND-60配制的42种农药乳油制剂中,溴氰菊酯、高效氯氟氰菊酯、毒死蜱等30种制剂(71.4%)有良好的匹配稳定性.可见松脂基植物油具有替代轻芳烃溶剂用于农药乳油制剂的潜力.

       

      Abstract: The flash point, volatility, pesticide solubility and stability of the pine oleoresin-based plant oils were measured for the purpose of development of natural alternatives of aromatic solvents in pesticide formulation. The results showed that the flash points of the 4 types of pine oleoresin-based plant oils were all above 35 ℃, which were obviously higher than that of the control solvent xylene. Under test temperature of 25 ℃, the volatility of the pine oleoresin-based plant oils for 8 h were less than 45.9%, with 2.1% of the least volatility of ND-100, whereas the volatility of xylene was 100%. The solubility of pine oleoresin-based plant oil ND-60 against the technical materials of 47 pesticides showed that 6 pesticides (12.8%), namely emamectin benzoate,fenbutatin-oxide, flusilazole, tebuconazole, lambda-cyhalothrin and azocyclotin, had remarkablely higher solubility than that in the control solvent of xylene, while 15 pesticides (31.9%), including spinosad and methidathion, were relatively less soluble in comparison with that in xylene. Measurements of the qualities of 42 emulsifiable concentrate preparations indicated that 30 preparations (71.4%),especially the preparations of deltamethrin, lambda-cyhalothrin and chlorpyrifos, exhibited qualified compatibility and stability in ND-60. These results suggested a positive potential of pine oleoresin-based plant oils as natural alternatives of aromatic solvents in the application of pesticide formulation.

       

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