周晓华,陈实,黄鹤,乐学义,刘洁珍. 邻菲咯啉-氨基酸铜(Ⅱ)三元混配配合物的合成及表征[J]. 华南农业大学学报, 2004, 25(2): 115-117. DOI: 10.7671/j.issn.1001-411X.2004.02.030
    引用本文: 周晓华,陈实,黄鹤,乐学义,刘洁珍. 邻菲咯啉-氨基酸铜(Ⅱ)三元混配配合物的合成及表征[J]. 华南农业大学学报, 2004, 25(2): 115-117. DOI: 10.7671/j.issn.1001-411X.2004.02.030
    ZHOU Xiao-hua,CHEN Shi,HUANG He,LE Xue-yi,LIU Jie-zhen. Synthesis and characterization of copper(Ⅱ) ternary mixed-ligand complexes with 1,10-phenanthroline and L-α-amino acid[J]. Journal of South China Agricultural University, 2004, 25(2): 115-117. DOI: 10.7671/j.issn.1001-411X.2004.02.030
    Citation: ZHOU Xiao-hua,CHEN Shi,HUANG He,LE Xue-yi,LIU Jie-zhen. Synthesis and characterization of copper(Ⅱ) ternary mixed-ligand complexes with 1,10-phenanthroline and L-α-amino acid[J]. Journal of South China Agricultural University, 2004, 25(2): 115-117. DOI: 10.7671/j.issn.1001-411X.2004.02.030

    邻菲咯啉-氨基酸铜(Ⅱ)三元混配配合物的合成及表征

    Synthesis and characterization of copper(Ⅱ) ternary mixed-ligand complexes with 1,10-phenanthroline and L-α-amino acid

    • 摘要: 合成了3种邻菲咯啉(Phen) 氨基酸铜(Ⅱ)的配合物:Cu(Phen)(L val)·ClO4·H2O、Cu(Phen)(L ala)·ClO4·0 5H2O和Cu(Phen)(L arg)·2ClO4·0 5H2O(L val:缬氨酸;L ala:丙氨酸:L arg:精氨酸).用元素分析、摩尔电导、红外光谱和电子吸收光谱等手段对配合物进行了表征,结果表明:邻菲咯啉作为双齿配体参与配位,3种氨基酸皆以α-氨基N和羧基O与中心Cu2+配位.

       

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